Spectroscopic Techniques and Hindered Molecular Motion
Spectroscopic Techniques and Hindered Molecular Motion presents a united theoretical approach to studying classical local thermal motion of small molecules and molecular fragments in crystals by spectroscopic techniques. Mono- and polycrystalline case studies demonstrate performance validity. The book focuses on small molecules and molecular fragments such as N2 HCl CO2 CH4 H2O NH4 BeF4 NH3 CH2 CH3 C6H6 SF6 and other symmetrical atomic formations which exhibit local hindered motion in molecular condensed media: molecular and ionic crystals molecular liquids liquid crystals polymeric solids and biological objects. It reviews the state of studying the hindered molecular motion (HMM) phenomenon and the experimental works on the basis of the latest theoretical research. Case StudiesPhysical models of hindered molecular motionGeneral solution of the stochastic problem for the hindered molecular motion in crystalsFormulae of the angular autocorrelation function symmetrized on the crystallographic point symmetry groups Formulae of the spectral line shapes concerning the dielectric infrared Raman nuclear magnetic relaxation and neutron scattering spectroscopy in the presence of the hindered molecular motionExperimental probation of the theoretical outcomesProton relaxation in three-atomic molecular fragments undergoing axial symmetry hindered motion Structural distortion in the ordered phase of crystalline ammonium chlorideOrganic compounds polymers pharmaceutical products and biological systems consist of the molecular fragments which possess rotational or conformational degrees of freedom or an atomic exchange within the fragme
